Special Reactions of Carbonyl Compounds

IMPORTANT

Special Reactions of Carbonyl Compounds: Overview

This Topic covers sub-topics such as Benzoin Condensation, Claisen Condensation Reaction, Wittig Reaction, Beckmann's Rearrangement, Schmidt Reaction, Claisen-Schmidt Reaction, MPV Reduction and, Benzil- Benzilic acid Rearrangement

Important Questions on Special Reactions of Carbonyl Compounds

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IMPORTANT

Compound which gives intramolecular aldol reaction?

MEDIUM
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Why propanal undergoes oxidation reaction faster than the propanone?

EASY
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Aldehydes are easily oxidesed than the ketone.

MEDIUM
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Why aldehydes are easily oxidised compared to ketone?

HARD
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The reduction of acetone by Mg-Hg gives:

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Identify the products in the following reaction.

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In the given reaction sequence what will be the final product 'T'?

C6H5-CH=OKCN/ΔRPCCS  ii Acidificationi conc KOHT

 

HARD
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Which of the following keto esters is /are not likely to have been prepared by a Claisen condensation?

EASY
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In the below reaction, which product is formed?

C6H5CHO+CH3COCH3 OH-P 

HARD
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Aldehydes can undergo aldol condensations and Cannizzaro reactions depending upon the reaction conditions.
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In which of the reaction α, β -unsaturated aldehyde, ketone or acid is not the main product?

EASY
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Which of the following named reaction is not used for introducing a - COOH group?

HARD
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The first two steps of the above set of reactions involve which reaction?

EASY
IMPORTANT

The reaction given below is an example of

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